پایان نامه مدل‌ سازی ریفرمر کاتالیستی مونولیتی خودگرما زا برای تولید هیدروژن برای پیل‌ های سوختی

فهرست:

فصل 1: مقدمه  1

1-1- مقدمه. 2

فصل 2: مروری بر پیشینه تحقیق   6

2-1- مقدمه. 7

2-2- ریفرمینگ هیدروکربن‌ها 7

2-2-1- ریفرمینگ با بخار آب... 7

2-2-2- ریفرمینگ اکسایش جزئی... 9

2-2-3- ریفرمینگ خودگرمازا 11

2-3- مکانیزم واکنش برای ریفرمینگ متان.. 12

2-3-1- مدلهای سینتیکی برای ریفرمنیگ متان.. 14

2-3-2- مدلهای سینتیکی برای احتراق متان.. 18

2-3-3- مدلهای سینتیکی برای واکنش شیفت آب- گاز. 20

2-4- راکتورهای مورد استفاده برای فرآیند ریفرمینگ..... 21

2-5- مدل‌سازی‌های صورت گرفته برای راکتورهای مونولیتی... 22

2-6- نتیجه گیری... 33

فصل 3: ارائه‌ی مدل‌سازی   34

3-1- مقدمه. 35

3-2- مشخصات راکتور مونولیتی مدل‌سازی شده. 35

3-3- فرضیات و معادلات استفاده شده در مدل‌سازی... 37

3-3-1- مدل‌سازی مکانیزم واکنش..... 43

3-3-2- روابط سینتیکی برای ریفرمینگ خودگرمازای متان بر روی کاتالیست روتنیم  44

3-4- نتیجه‌گیری... 47

فصل 4: نتایج و بحث    49

4-1- مقدمه. 50

4-2- بررسی صحت مدل‌سازی... 50

4-1-1- مقایسه با نتایج آزمایشگاهی... 50

4-3- اثر میزان اکسیژن ورودی... 57

4-4- اثر میزان بخار‌آب ورودی... 62

4-5- بررسی اثر دمای گاز ورودی... 69

4-6- نتیجه‌گیری... 75

فصل 5: جمع‌بندی و پیشنهادات   76

5-1- مقدمه. 77

5-1-1- پیشنهادها 78

مراجع   79

پیوست           

منبع:

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